1.14.14.147: 22alpha-hydroxysteroid 23-monooxygenase
This is an abbreviated version!
For detailed information about 22alpha-hydroxysteroid 23-monooxygenase, go to the full flat file.
Word Map on EC 1.14.14.147
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1.14.14.147
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brassinosteroids
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steroid
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cyp90b1
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dwarf
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brassinolide
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campestanol
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organ-specific
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br-deficient
- 1.14.14.147
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brassinosteroids
- steroid
- cyp90b1
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dwarf
- brassinolide
- campestanol
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organ-specific
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br-deficient
Reaction
Synonyms
3-epi-6-deoxocathasterone 23-monooxygenase, 3-epi-6-deoxocathasterone,[reduced NADPH—hemoprotein reductase]:oxygen oxidoreductase (C-23-hydroxylating), CYP90C1, CYP90C1/ROTUNDIFOLIA3, CYP90D1, cytochrome P450 90C1, EC 1.14.13.112, ROT3
ECTree
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Substrates Products
Substrates Products on EC 1.14.14.147 - 22alpha-hydroxysteroid 23-monooxygenase
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REACTION DIAGRAM
(22S)-22-hydroxycampest-4-en-3-one + [reduced NADPH-hemoprotein reductase] + O2
(22R,23R)-22,23-dihydroxycampest-4-en-3-one + [oxidized NADPH-hemoprotein reductase] + H2O
(22S)-22-hydroxycampesterol + [reduced NADPH-hemoprotein reductase] + O2
(22R,23R)-22,23-dihydroxycampesterol + [oxidized NADPH-hemoprotein reductase] + H2O
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?
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + [reduced NADPH-hemoprotein reductase] + O2
3-dehydro-6-deoxoteasterone + [oxidized NADPH-hemoprotein reductase] + H2O
3-epi-6-deoxocathasterone + [reduced NADPH-hemoprotein reductase] + O2
6-deoxotyphasterol + [oxidized NADPH-hemoprotein reductase] + H2O
6-deoxocathasterone + [reduced NADPH-hemoprotein reductase] + O2
6-deoxoteasterone + [oxidized NADPH-hemoprotein reductase] + H2O
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?
typhasterol + [reduced NADPH-hemoprotein reductase] + O2
castasterone + [oxidized NADPH-hemoprotein reductase] + H2O
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?
(22R,23R)-22,23-dihydroxycampest-4-en-3-one + [oxidized NADPH-hemoprotein reductase] + H2O
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?
(22S)-22-hydroxycampest-4-en-3-one + [reduced NADPH-hemoprotein reductase] + O2
(22R,23R)-22,23-dihydroxycampest-4-en-3-one + [oxidized NADPH-hemoprotein reductase] + H2O
i.e. (22S,24R)-22-hydroxyergost-4-en-3-one
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3-dehydro-6-deoxoteasterone + [oxidized NADPH-hemoprotein reductase] + H2O
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(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + [reduced NADPH-hemoprotein reductase] + O2
3-dehydro-6-deoxoteasterone + [oxidized NADPH-hemoprotein reductase] + H2O
i.e (22S)-22-hydroxycampest-4-en-3-one. C-23 hydroxylation shortcuts bypass campestanol, 6-deoxocathasterone, and 6-deoxoteasterone and lead directly from (22S,24R)-22-hydroxy-5alpha-ergostan-3-one and 3-epi-6-deoxocathasterone to 3-dehydro-6-deoxoteasterone and 6-deoxotyphasterol
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6-deoxotyphasterol + [oxidized NADPH-hemoprotein reductase] + H2O
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3-epi-6-deoxocathasterone + [reduced NADPH-hemoprotein reductase] + O2
6-deoxotyphasterol + [oxidized NADPH-hemoprotein reductase] + H2O
C-23 hydroxylation shortcuts bypass campestanol, 6-deoxocathasterone, and 6-deoxoteasterone and lead directly from (22S,24R)-22-hydroxy-5alpha-ergostan-3-one and 3-epi-6-deoxocathasterone to 3-dehydro-6-deoxoteasterone and 6-deoxotyphasterol
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