1.14.14.108: 2,5-diketocamphane 1,2-monooxygenase

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For detailed information about 2,5-diketocamphane 1,2-monooxygenase, go to the full flat file.

Reaction

Synonyms

2,5-diketocamphane 1,2-monooxygenase, 2,5-diketocamphane lactonizing enzyme, 2,5-diketocamphane monooxygenase, 2,5-DKCMO, 2,5-DKCMO-1, 2,5-DKCMO-2, 3,6-diketocamphane 1,6-monooxygenase, camE25-1, camE25-2, camphor ketolactonase I, EC 1.14.13.162, EC 1.14.15.2, ketolactonase I, More, oxygenase, camphor 1,2-mono

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.14.108 2,5-diketocamphane 1,2-monooxygenase

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Results	in table
2	Activating Compound
33	AA Sequence
2	Application
1	CAS Registry Number
2	Cloned(Commentary)
13	Cofactor
2	Crystallization (Commentary)
2	General Information
11	Inhibitors
6	KM Value [mM]
8	Localization
4	Metals/Ions
22	Molecular Weight [Da]
10	Natural Substrates/ Products (Substrates)
72	Organism
4	Pathway
7	pH Optimum
2	pH Range
12	Purification (Commentary)
17	Reaction
9	Reaction Type
25	Reference
1	Renatured (Commentary)
11	Specific Activity [micromol/min/mg]
3	Storage Stability
77	Substrates and Products (Substrate)
13	Subunits
37	Synonyms
1	Systematic Name
5	Temperature Optimum [°C]
3	Temperature Stability [°C]
7	Turnover Number [1/s]

Systematic Name

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Systematic Name on EC 1.14.14.108 - 2,5-diketocamphane 1,2-monooxygenase

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SYSTEMATIC NAME

IUBMB Comments

(+)-bornane-2,5-dione,FMNH2:oxygen oxidoreductase (1,2-lactonizing)

A Baeyer-Villiger monooxygenase isolated from camphor-grown strains of Pseudomonas putida and encoded on the cam plasmid. Involved in the degradation of (+)-camphor. Requires a dedicated NADH-FMN reductase [cf. EC 1.5.1.42, FMN reductase (NADH)] [1-3]. Can accept several bicyclic ketones including (+)- and (-)-camphor [6] and adamantanone [4]. The product spontaneously converts to [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate.