1.14.14.98: protopine 6-monooxygenase
This is an abbreviated version!
For detailed information about protopine 6-monooxygenase, go to the full flat file.
Word Map on EC 1.14.14.98
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1.14.14.98
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sanguinarine
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somniferum
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papaver
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benzylisoquinoline
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papaveraceae
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elicitors
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stylopine
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alkaloids
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allocryptopine
- 1.14.14.98
- sanguinarine
- somniferum
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papaver
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benzylisoquinoline
- papaveraceae
- elicitors
- stylopine
- alkaloids
- allocryptopine
Reaction
Synonyms
CYP82N2v2, CYP82N3, EC 1.14.13.55, Oxygenase, protropine 6-mono-, P6H, protopine 6-hydroxylase, Protopine-6-hydroxylase
ECTree
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Substrates Products
Substrates Products on EC 1.14.14.98 - protopine 6-monooxygenase
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REACTION DIAGRAM
13-oxoprotopine + [reduced NADPH-hemoprotein reductase] + O2
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allocryptopine + [reduced NADPH-hemoprotein reductase] + O2
6-hydroxyallocryptopine + [oxidized NADPH-hemoprotein reductase] + H2O
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corycavine + [reduced NADPH-hemoprotein reductase] + O2
corynoloxine + [oxidized NADPH-hemoprotein reductase] + H2O
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protopine + [reduced NADPH-hemoprotein reductase] + O2
6-hydroxyprotopine + [oxidized NADPH-hemoprotein reductase] + H2O
protopine + [reduced NADPH-hemoprotein reductase] + O2
dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
6-hydroxyprotopine + [oxidized NADPH-hemoprotein reductase] + H2O
i.e. dihydrosanguinarine
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protopine + [reduced NADPH-hemoprotein reductase] + O2
6-hydroxyprotopine + [oxidized NADPH-hemoprotein reductase] + H2O
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hydroxylation of protopine by protopine 6-hydroxylase produces the unstable intermediate 6-hydroxyprotopine that spontaneously rearranges to form dihydrosanguinarine
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dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
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protopine + [reduced NADPH-hemoprotein reductase] + O2
dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
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protopine + [reduced NADPH-hemoprotein reductase] + O2
dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
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protopine + [reduced NADPH-hemoprotein reductase] + O2
dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
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protopine + [reduced NADPH-hemoprotein reductase] + O2
dihydrosanguinarine + [oxidized NADPH-hemoprotein reductase] + H2O
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the enzyme is specifically present in different plant species that produce benzo[c]phenanthridine alkaloids in culture
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additional information
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the enzyme is specifically present in different plant species that produce benzo[c]phenanthridine alkaloids in culture
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additional information
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the enzyme is specifically present in different plant species that produce benzo[c]phenanthridine alkaloids in culture
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additional information
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no activity with protopine-N-oxide, reticuline, scoulerine, and N-methyl stylopine
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additional information
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no activity with protopine-N-oxide, reticuline, scoulerine, and N-methyl stylopine
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additional information
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the enzyme is specifically present in different plant species that produce benzo[c]phenanthridine alkaloids in culture
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additional information
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the enzyme is specifically present in different plant species that produce benzo[c]phenanthridine alkaloids in culture
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