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1.14.14.58: trimethyltridecatetraene synthase

This is an abbreviated version!
For detailed information about trimethyltridecatetraene synthase, go to the full flat file.

Reaction

(6E,10E)-geranyllinalool
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(3E,7E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene
+
[oxidized NADPH-hemoprotein reductase]
+
but-3-en-2-one
+ 2 H2O

Synonyms

At3g25180, CYP82G1, CYP92C5, CYP92C6, cytochrome P450 82G1, DMNT homoterpene synthase, DMNT synthase, DMNT/TMTT homoterpene synthase, TMTT homoterpene synthase, TMTT synthase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.58 trimethyltridecatetraene synthase

Systematic Name

Systematic Name on EC 1.14.14.58 - trimethyltridecatetraene synthase

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SYSTEMATIC NAME
IUBMB Comments
(6E,10E)-geranyllinalool,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase
A cytochrome P-450 (heme-thiolate) protein isolated from the plants Arabidopsis thaliana (thale cress) and Zea mays (maize). It forms this C16 homoterpene in response to herbivore attack. In vitro some variants of the enzyme also convert (3S,6E)-nerolidol to (3E)-4,8-dimethylnona-1,3,7-triene (see EC 1.14.14.59, dimethylnonatriene synthase).