1.14.14.111: 9beta-pimara-7,15-diene oxidase

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For detailed information about 9beta-pimara-7,15-diene oxidase, go to the full flat file.

Reaction

Synonyms

CYP99A3, EC 1.14.13.144

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.14.111 9beta-pimara-7,15-diene oxidase

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Results	in table
2	AA Sequence
2	Cloned(Commentary)
3	General Information
2	kcat/KM [mM/s]
2	KM Value [mM]
2	Organism
3	Pathway
4	Reaction
2	Reference
8	Substrates and Products (Substrate)
3	Synonyms
1	Systematic Name
2	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 1.14.14.111 - 9beta-pimara-7,15-diene oxidase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

9beta-pimara-7,15-diene + [reduced NADPH-hemoprotein reductase] + O2

3beta-hydroxy-9beta-pimara-7,15-dien-19,6beta-olide + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

-

-

680848

-

-

?

syn-pimara-7,15-diene + [reduced NADPH-hemoprotein reductase] + O2

syn-pimaradien-19-ol + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

-

718217

-

-

?

syn-pimaradien-19-al + [reduced NADPH-hemoprotein reductase] + O2

syn-pimaradien-19-oate + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

-

718217

-

-

?

syn-pimaradien-19-ol + [reduced NADPH-hemoprotein reductase] + O2

syn-pimaradien-19-al + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

-

718217

-

-

?

syn-stemod-13(17)-ene + [reduced NADPH-hemoprotein reductase] + O2

syn-stemoden-19-ol + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19

718217

-

-

?

syn-stemoden-19-al + [reduced NADPH-hemoprotein reductase] + O2

syn-stemoden-19-oate + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19

718217

-

-

?

syn-stemoden-19-ol + [reduced NADPH-hemoprotein reductase] + O2

syn-stemoden-19-al + [oxidized NADPH-hemoprotein reductase] + H2O

Oryza sativa

Q0JF01

about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19

718217

-

-

?

additional information

?

-

2 entries

additional information

?

-

Oryza sativa

Q0JF01

CYP99A3 catalyzes consecutive oxidations of the C19 methyl group of the momilactone precursor syn-pimara-7,15-diene to form, sequentially, syn-pimaradien-19-ol, syn-pimaradien-19-al, and syn-pimaradien-19-oate

718217

-

-

?

additional information

?

-

Oryza sativa

-

CYP99A3 catalyzes consecutive oxidations of the C19 methyl group of the momilactone precursor syn-pimara-7,15-diene to form, sequentially, syn-pimaradien-19-ol, syn-pimaradien-19-al, and syn-pimaradien-19-oate

718217

-

-

?