1.14.14.104: vinorine hydroxylase
This is an abbreviated version!
For detailed information about vinorine hydroxylase, go to the full flat file.
Reaction
Synonyms
CYP5437, CYP82S18, cytochrome P450_5437, EC 1.14.13.75, vinorine hydroxylase
ECTree
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Substrates Products
Substrates Products on EC 1.14.14.104 - vinorine hydroxylase
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REACTION DIAGRAM
vinorine + [reduced NADPH-hemoprotein reductase] + O2
vomilenine + [oxidized NADPH-hemoprotein reductase] + H2O
vomilenine + [oxidized NADPH-hemoprotein reductase] + H2O
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?
vinorine + [reduced NADPH-hemoprotein reductase] + O2
vomilenine + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
vinorine + [reduced NADPH-hemoprotein reductase] + O2
vomilenine + [oxidized NADPH-hemoprotein reductase] + H2O
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enzyme is involved in the biosynthesis of the alkaloid ajmaline
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the enzyme also catalyzes the non-oxidative isomerization of the ajmaline precursor vomilenine to perakine
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additional information
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the enzyme also catalyzes the non-oxidative isomerization of the ajmaline precursor vomilenine to perakine
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-
?
additional information
?
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product analysis by NMR spectroscopy. The stereoselectivity of the enzyme cannot be determined, since the vomilenine isomers cannot be separated
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additional information
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product analysis by NMR spectroscopy. The stereoselectivity of the enzyme cannot be determined, since the vomilenine isomers cannot be separated
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-
?
additional information
additional information
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the enzyme also catalyzes the non-oxidative isomerization of the ajmaline precursor vomilenine to perakine
-
-
?
additional information
additional information
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-
the enzyme also catalyzes the non-oxidative isomerization of the ajmaline precursor vomilenine to perakine
-
-
?