1.14.13.69: alkene monooxygenase
This is an abbreviated version!
For detailed information about alkene monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.69
-
1.14.13.69
-
epoxidation
-
xanthobacter
-
vinyl
-
diiron
-
nocardioides
-
4-monooxygenase
-
propyne
-
dinuclear
-
rhodochrous
-
smmos
-
epoxygenation
-
epoxyethane
-
corallinus
-
autotrophicus
- 1.14.13.69
-
epoxidation
- xanthobacter
-
vinyl
-
diiron
- nocardioides
-
4-monooxygenase
- propyne
-
dinuclear
- rhodochrous
-
smmos
-
epoxygenation
- epoxyethane
- corallinus
- autotrophicus
Reaction
Synonyms
AkMO, alkene epoxygenase, alkene monooxygenase, AMO, ethene MO, EtnABCD, EtnC, etnD, IsoMO, isoprene monooxygenase, More, PmoABCD, propene MO, propene monooxygenase, XAMO
ECTree
Advanced search results
Substrates Products
Substrates Products on EC 1.14.13.69 - alkene monooxygenase
Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
REACTION DIAGRAM
1-butene + NADH + H+ + O2
2-ethyloxirane + NAD+ + H2O
-
best substrate
-
-
?
ethene + NADH + H+ + O2
oxirane + NAD+ + H2O
-
high activity
-
-
?
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
constitutive enzyme
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
constitutive enzyme
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
best substrate
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
best substrate
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
-
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
induction by propylene and propylene oxide and a variety of aliphatic and chlorinated alkenes and epoxides
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
the inducible enzyme is central to the bacterial metabolism of aliphatic alkenes. Enzyme is expressed during growth of Xanthobacter on aliphatic alkenes or epoxides and repressed during growth on other carbon sources
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
induction by propylene and propylene oxide and a variety of aliphatic and chlorinated alkenes and epoxides
-
-
?
propene + NADH + H+ + O2
1,2-epoxypropane + NAD+ + H2O
-
the inducible enzyme is central to the bacterial metabolism of aliphatic alkenes. Enzyme is expressed during growth of Xanthobacter on aliphatic alkenes or epoxides and repressed during growth on other carbon sources
-
-
?
propene + NADH + O2
1,2-epoxypropane + NAD+ + H2O
-
enables the growth on propene as sole carbon and energy source
-
-
?
propene + NADH + O2
1,2-epoxypropane + NAD+ + H2O
-
enables the growth on propene as sole carbon and energy source
-
-
?
2,3-dichlorooxirane + NAD+ + H2O
-
-
-
-
?
trans-1,2-dichloroethylene + NADH + H+ + O2
2,3-dichlorooxirane + NAD+ + H2O
-
-
-
-
?
2,2,3-trichlorooxirane + NAD+ + H2O
-
-
-
-
?
trichloroethylene + NADH + H+ + O2
2,2,3-trichlorooxirane + NAD+ + H2O
-
-
-
-
?
trichloroethylene + NADH + H+ + O2
2,2,3-trichlorooxirane + NAD+ + H2O
-
-
-
-
?
trichloroethylene + NADH + H+ + O2
2,2,3-trichlorooxirane + NAD+ + H2O
-
-
-
-
?
?
-
-
EtnABCD is specialized for the oxidation of gaseous alkenes (C2 to C4), and its activity is much lower on liquid alkenes (C5 to C8), substrate specificity, overview. Cyclopentene and styrene are poor substrates
-
-
-
additional information
?
-
-
PmoABCD is specialized for the oxidation of gaseous alkenes (C2 to C4), and its activity is much lower on liquid alkenes (C5 to C8), substrate specificity, overview. Cyclopentene is a poor substrate
-
-
-
additional information
?
-
-
EtnABCD is specialized for the oxidation of gaseous alkenes (C2 to C4), and its activity is much lower on liquid alkenes (C5 to C8), substrate specificity, overview. Cyclopentene and styrene are poor substrates
-
-
-
additional information
?
-
-
PmoABCD is specialized for the oxidation of gaseous alkenes (C2 to C4), and its activity is much lower on liquid alkenes (C5 to C8), substrate specificity, overview. Cyclopentene is a poor substrate
-
-
-
additional information
?
-
-
alkene monooxygenase and epoxyalkane:coenzyme M transferase are the initial enzymes of vinyl chloride and ethene biodegradation in strain JS614
-
-
?
additional information
?
-
-
ethene and propene are transformed by ethene-grown and propene-grown/EtO-induced JS614 to ethene oxide and propene oxide, respectively
-
-
?
additional information
?
-
Nocardioides sp. JS614 / ATCC BAA-499
-
alkene monooxygenase and epoxyalkane:coenzyme M transferase are the initial enzymes of vinyl chloride and ethene biodegradation in strain JS614
-
-
?
additional information
?
-
Nocardioides sp. JS614 / ATCC BAA-499
-
ethene and propene are transformed by ethene-grown and propene-grown/EtO-induced JS614 to ethene oxide and propene oxide, respectively
-
-
?
additional information
?
-
-
the enzyme is a three-component system encoded by the 4-gene operon amoABCD, which catalyzes the stereoselective epoxidation of aliphatic alkenes yielding primarily the R enantiomer
-
-
?
additional information
?
-
-
the enzyme is a three-component system encoded by the 4-gene operon amoABCD, which catalyzes the stereoselective epoxidation of aliphatic alkenes yielding primarily the R enantiomer
-
-
?
additional information
?
-
-
product identification after reaction of th recombinant enzyme with isoprene by GC-MS
-
-
-
additional information
?
-
-
alternative alkene cleavage mechanism by incorporating 2 oxygen atoms of different oxygen molecules
-
-
?
additional information
?
-
the enzyme catalyses the asymmetric epoxidation of a broad range of alkenes, stereo- and regioselectivity, residues Asn34 and Arg57 are involved, AMO requires a small catalytic coupling/effector protein, AamD, substitution of AamD with IsoD, the coupling protein from the closely related isoprene monooxygenase, changes the regioselectivity of toluene hydroxylation and stereoselectivity of styrene epoxidation, although this is accompanied by a high level of uncoupling, overview
-
-
?