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EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
2.2.1.1
2 D-xylulose 5-phosphate
reversible single substrate reaction, about 6% of the double-substrate reaction rate
Homo sapiens
glyceraldehyde 3-phosphate + glycolaldehyde
-
?
2.2.1.1
2 hydroxypyruvate
-
Saccharomyces cerevisiae
2 glyoxylic acid + erythrulose
-
ir
2.2.1.1
2 propanal + 2 lithium beta-hydroxypyruvate
-
Geobacillus stearothermophilus
(3S)-1,3-dihydroxypentan-2-one + (3R)-1,3-dihydroxypentan-2-one + 2 CO2 + 2 Li+
-
ir
2.2.1.1
2 propanal + 2 lithium beta-hydroxypyruvate
use of lithium beta-hydroxypyruvate as a donor renders the reaction irreversible
Escherichia coli
(3S)-1,3-dihydroxypentan-2-one + (3R)-1,3-dihydroxypentan-2-one + 2 CO2 + 2 Li+
wild-type, 58% enantiomeric excess for 3S-product
r
2.2.1.1
2 pyruvate
-
Escherichia coli
erythrulose
-
?
2.2.1.1
2-deoxy-D-erythrose 4-phosphate + ?
-
Saccharomyces cerevisiae
?
-
?
2.2.1.1
2-deoxy-D-ribose 5-phosphate + ?
-
Saccharomyces cerevisiae
?
-
?
2.2.1.1
2-methoxyethanal + glycolaldehyde
-
Geobacillus stearothermophilus
(3S)-1,3-dihydroxy-4-methoxybutan-2-one
-
?
2.2.1.1
2-phenylethanal + hydroxypyruvate
-
Geobacillus stearothermophilus
(S)-1,3-dihydroxy-4-phenylbutan-2-one + CO2
-
ir
2.2.1.1
3-formylbenzoic acid + hydroxypyruvate
-
Escherichia coli
3-(1,3-dihydroxy-2-oxopropyl)benzoic acid + CO2
-
?
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