Literature summary for 1.2.3.4 extracted from

Jena, P.; Acharya, A.; Mundlapati, V.; Dash, A.; Biswal, H.
Kinetics and mechanistic study of the reduction of Mn III by oxalate in Salophen scaffold relevance to oxalate oxidase (2018), J. Chem. Sci., 130, 123 .

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Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

General Information

General Information	Comment	Organism
metabolism	trans-MnIII(salophen)(OH2)2+ and bioxalate (HOX-)in aqueous medium equilibrate rapidly to trans-MnIII(salophen)(OH2)(HOX) followed by the acid dissociation equilibrium to the (aqua)monooxalato complex. The slow redox reactions of trans-MnIII(salophen)(OH2)(HOX/OX)0/- with H2OX, HOX-, OX2-obey second order kinetics satisfying 2:1 stoichiometry. The products are MnII and CO2. The sequence of the redox activity of the oxalato complexes reflects the potential role of noncovalent interaction i.e. H-bonding, governing the proton controlled electron transfer process	synthetic construct

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Release 2023.1 (January 2023)