Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
pyruvate + phosphate + O2 + H2O | Lactiplantibacillus plantarum | specifically favors phosphorylysis rather than hydrolysis, decarboxylation step not rate-limiting | acetyl phosphate + CO2 + H2O2 | - |
ir |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Lactiplantibacillus plantarum | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
pyruvate + phosphate + 2,6-dichlorophenolindophenol + H2O | artificial electron acceptor 2,6-dichlorophenolindophenol reacts with the carbanion of the enzyme-bound intermediate hydroxyethyl-thiamine diphosphate | Lactiplantibacillus plantarum | acetyl phosphate + CO2 + reduced 2,6-dichlorophenolindophenol + H2O2 | - |
? | |
pyruvate + phosphate + O2 | reduction of enzyme by its substrate, pyruvate, in the absence of oxygen | Lactiplantibacillus plantarum | acetyl phosphate + CO2 + H2O2 | - |
ir | |
pyruvate + phosphate + O2 + H2O | specifically favors phosphorylysis rather than hydrolysis, decarboxylation step not rate-limiting | Lactiplantibacillus plantarum | acetyl phosphate + CO2 + H2O2 | - |
ir |
Turnover Number Minimum [1/s] | Turnover Number Maximum [1/s] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
16 | - |
pyruvate | electron acceptor: O2 | Lactiplantibacillus plantarum | |
26 | - |
pyruvate | electron acceptor: 2,6-dichlorophenolindophenol | Lactiplantibacillus plantarum |
Cofactor | Comment | Organism | Structure |
---|---|---|---|
FAD | reduction of FAD via a two-step single-electron transfer | Lactiplantibacillus plantarum | |
thiamine diphosphate | - |
Lactiplantibacillus plantarum |